Electrophilic induced asymmetric boronate rearrangements via CAPT catalysis. A n...
Electrophilic induced asymmetric boronate rearrangements via CAPT catalysis. A novel approach towards the formal trifunctionalization of alkenes.
This proposal describes an unprecedented, enantioselective haloborylation reaction through the innovative application of chiral anion phase-transfer (CAPT) catalysis to electrophilic-induced boronate rearrangements. Beyond the dev...
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Información proyecto HALOBORYLATION
Duración del proyecto: 31 meses
Fecha Inicio: 2017-03-09
Fecha Fin: 2019-10-31
Fecha límite de participación
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Descripción del proyecto
This proposal describes an unprecedented, enantioselective haloborylation reaction through the innovative application of chiral anion phase-transfer (CAPT) catalysis to electrophilic-induced boronate rearrangements. Beyond the development of an orthogonal approach towards the formal trifunctionalization of alkenes, the proposed methodology provides easy access to biologically and synthetically important products, and is anticipated to have great impact in the area of diversity oriented synthesis.