Hola,
¿eres nuevo aquí?

Regístrate gratis y conecta tu empresa con financiación pública, partners y proyectos.

Tengo cuenta

Regístrate

Ver video

2O2ACTIVATION

Financiado

Cerrado

Development of Direct Dehydrogenative Couplings mediated by Dioxygen

The field of C-H bond activation has evolved at an exponential pace in the last 15 years. What appeals most in those novel synthetic techniques is clear: they bypass the pre-activation steps usually required in traditional cross-c... ver más

31/08/2022

RWTH AACHEN

1M€

Presupuesto del proyecto: 1M€

Líder del proyecto

RHEINISCHWESTFAELISCHE TECHNISCHE HOCHSCHULE... No se ha especificado una descripción o un objeto social para esta compañía.

TRL 4-5

Fecha límite participación Sin fecha límite de participación.

Ver 3 Participantes

Financiación concedida El organismo H2020 notifico la concesión del proyecto el día 2022-08-31

ERC-2016-STG: ERC Starting Grant

I+D

Cerrada hace 9 años

0% 100%

Información adicional privada

No hay información privada compartida para este proyecto. Habla con el coordinador.

3 Participantes

RWTH AACHEN

1.08M€ | Lider

CONSERVAS MARTIKO

RHEINLAND-PFALZISCHE TECHNIS...

408.99K€ | Participante

Conecta tu I+D

¿Tienes un proyecto y buscas un partner? Gracias a nuestro motor inteligente podemos recomendarte los mejores socios y ponerte en contacto con ellos. Te lo explicamos en este video

Proyectos interesantes

CTQ2017-88171-P CATALISIS FOTOREDOX HETEROGENEA EN REACCIONES SOSTENIBLES DE... 91K€ Cerrado

HurdlingOxoWall Late First Row Transition Metal Oxo Complexes for C H Bond A... 1M€ Cerrado

AU-DOUBLEC-H Gold catalysed dehydrogenative cross coupling of arenes 222K€ Cerrado

PID2019-104159GB-I00 SISTEMAS ORGANOMETALICOS PARA TRANSFORMACIONES ESTEQUIOMETRI... 61K€ Cerrado

BES-2014-070441 INVESTIGACIONES MECANISTICAS PARA SINTESIS ORGANICA SOSTENIB... 88K€ Cerrado

ECHO-GRACADE Enantioselective C H Oxidation Guided by Rational Catalyst D... 2M€ Cerrado

Duración del proyecto: 70 meses Fecha Inicio: 2016-10-21
Fecha Fin: 2022-08-31

Líder del proyecto

RHEINISCHWESTFAELISCHE TECHNISCHE HOCHSCHULE... No se ha especificado una descripción o un objeto social para esta compañía.

TRL 4-5

Presupuesto del proyecto 1M€

Fecha límite de participación Sin fecha límite de participación.

Descripción del proyecto The field of C-H bond activation has evolved at an exponential pace in the last 15 years. What appeals most in those novel synthetic techniques is clear: they bypass the pre-activation steps usually required in traditional cross-coupling chemistry by directly metalating C-H bonds. Many C-H bond functionalizations today however, rely on poorly atom and step efficient oxidants, leading to significant and costly chemical waste, thereby seriously undermining the overall sustainability of those methods. As restrictions in sustainability regulations will further increase, and the cost of certain chemical commodities will rise, atom efficiency in organic synthesis remains a top priority for research. The aim of 2O2ACTIVATION is to develop novel technologies utilizing O2 as sole terminal oxidant in order to allow useful, extremely sustainable, thermodynamically challenging, dehydrogenative C-N and C-O bond forming coupling reactions. However, the moderate reactivity of O2 towards many catalysts constitutes a major challenge. 2O2ACTIVATION will pioneer the design of new catalysts based on the ultra-simple propene motive, capable of direct activation of O2 for C-H activation based cross-couplings. The project is divided into 3 major lines: O2 activation using propene and its analogues (propenoids), 1) without metal or halide, 2) with hypervalent halide catalysis, 3) with metal catalyzed C-H activation. The philosophy of 2O2ACTIVATION is to focus C-H functionalization method development on the oxidative event. Consequently, 2O2ACTIVATION breakthroughs will dramatically shortcut synthetic routes through the use of inactivated, unprotected, and readily available building blocks; and thus should be easily scalable. This will lead to a strong decrease in the costs related to the production of many essential chemicals, while preserving the environment (water as terminal by-product). The resulting novels coupling methods will thus have a lasting impact on the chemical industry.

Conecta tu I+D

Entra hoy

¿Olvidé mi contraseña?

Financiación

Empresas

CTIs/Universidades

Proyectos

Investigadores