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Elmar

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Redefining the landscape of ammonia electrooxidation, utilising molecular electr...

Redefining the landscape of ammonia electrooxidation, utilising molecular electrocatalysts Fuel cells represent highly efficient and non-polluting power devices that convert the chemical energy of a fuel into electrical power. Ammonia, as a fuel, is considered a potent alternative to the commonly used hydrogen because i... ver más

31/08/2026

207K€

Presupuesto del proyecto: 207K€

Líder del proyecto

UPPSALA UNIVERSITET No se ha especificado una descripción o un objeto social para esta compañía.

TRL 4-5

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Financiación concedida El organismo HORIZON EUROPE notifico la concesión del proyecto el día 2024-04-15

HORIZON-MSCA-2023-PF-01-01: MSCA Postdoctoral Fellowships 2023 ExpectedOutcome:Project results are expected to contribute to the following outcomes:

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No hay información privada compartida para este proyecto. Habla con el coordinador.

2 Participantes

206.89K€ | Lider

TUM

N.D. | Participante

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Duración del proyecto: 28 meses Fecha Inicio: 2024-04-15
Fecha Fin: 2026-08-31

Líder del proyecto

UPPSALA UNIVERSITET No se ha especificado una descripción o un objeto social para esta compañía.

TRL 4-5

Presupuesto del proyecto 207K€

Descripción del proyecto Fuel cells represent highly efficient and non-polluting power devices that convert the chemical energy of a fuel into electrical power. Ammonia, as a fuel, is considered a potent alternative to the commonly used hydrogen because it has a lower cost per unit of stored energy and benefits from a well-established production and distribution infrastructure. The electrochemical NH3 oxidation reaction (eAOR) typically relies on Pt-based electrocatalysts due to their low overpotential and remarkable selectivity for N2. However, their susceptibility to durability problems exacerbates their already high cost and limited availability. A few recent studies have reported molecular eAOR catalysts, but evaluate them under homogeneous conditions, which are rarely relevant to energy-related applications. To make feasible catalytic systems out of molecular catalysts, their heterogenisation on electrode surfaces is necessary. Within the MSCA postdoctoral fellowship 'Elmar', I aim to construct catalytic films for eAOR, by encapsulating non-noble metal molecular complexes in carbon-based supporting materials. Those hybrid electrocatalysts will undergo electrochemical assessment to determine their efficiency and durability, and will be compared to a reference Pt/C catalyst. The performance of each electrocatalyst will be optimized by tuning the micro-environment of the molecular complex inside the film, and rationalized based on spectroscopic and spectroelectrochemical investigations. Overall, I aspire to establish an exemplary methodology for constructing, optimizing, and rationalizing electrocatalysts based on simple non-noble metal complexes. My ultimate goal is to create robust eAOR catalysts capable of competing with Pt-based ones. This endeavour can significantly contribute to the development of fuel cell technologies, that are expected to play an important role in the decarbonization of the EU’s energy system.

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