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MN-LN SMMS

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Cerrado

Synthesis and characterization of Mn Ln polynuclear complexes with interesting m...

Synthesis and characterization of Mn Ln polynuclear complexes with interesting magnetic properties by the use of diol type ligands Nanoscopic magnetic materials are of increasing interest because of their potential use for ultrahigh – density information storage, quantum computing, sensing and biomedical applications. Among the various types of nanoscopic mag... ver más

31/12/2015

UCY

100K€

Presupuesto del proyecto: 100K€

Líder del proyecto

UNIVERSITY OF CYPRUS No se ha especificado una descripción o un objeto social para esta compañía.

TRL 4-5

Fecha límite participación Sin fecha límite de participación.

Financiación concedida El organismo FP7 notifico la concesión del proyecto el día 2015-12-31 No tenemos la información de la convocatoria

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1 Participantes

UCY

0.00€ | Lider

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Líder del proyecto

UNIVERSITY OF CYPRUS No se ha especificado una descripción o un objeto social para esta compañía.

TRL 4-5

Presupuesto del proyecto 100K€

Fecha límite de participación Sin fecha límite de participación.

Descripción del proyecto Nanoscopic magnetic materials are of increasing interest because of their potential use for ultrahigh – density information storage, quantum computing, sensing and biomedical applications. Among the various types of nanoscopic magnetic materials, single molecule magnets (SMMs) represent a family of promising, for use in the above mentioned technological applications, molecule – based magnetic materials. SMMs are molecular transition-metal clusters that retain their magnetization below a blocking temperature (TB or Tcritical) in the absence of an applied field. In order to employ molecule-based materials in technological applications it is important to prepare SMMs with larger thermodynamic barriers (U) and effective (kinetic) barriers (Ueff) to magnetization reversal and the synthesis of polynuclear heterometallic Mn/lanthanide (Ln) species seems an attractive approach for achieving this. The main idea behind this approach is to combine Mnn+ and Ln3+ ion’s significant spin and/or their large anisotropy to generate Mn/4f SMMs distinctly different from, and superior to, the homometallic ones. The specific scientific and technological objectives of this project include: 1) the preparation of new Mn-Ln-L (L = diol-type ligands) clusters and SMMs, 2) the development of new synthetic procedures to polynuclear Mn-Ln clusters and SMMs, and 3) the complete structural and magnetic characterization of the compounds. The complete magnetic and structural characterization of the compounds is essential in order to rationalize their magnetic properties on the basis of their structural characteristics and finally to achieve optimization of their SMM properties by performing controlled structural modifications.

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