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Shedding light on catalyst systems for a brighter future with green oxidation ch...

Shedding light on catalyst systems for a brighter future with green oxidation chemistry Sustainability in chemical synthesis requires that new methods and replacements for unsustainable existing methodologies should, where possible, focus on environmentally benign, atom- and energy-efficient processes that do not rel... ver más

31/10/2016

RIJKSUNIVERSITEIT...

2M€

Presupuesto del proyecto: 2M€

Líder del proyecto

RIJKSUNIVERSITEIT GRONINGEN No se ha especificado una descripción o un objeto social para esta compañía.

TRL 4-5

Fecha límite participación Sin fecha límite de participación.

Financiación concedida El organismo FP7 notifico la concesión del proyecto el día 2016-10-31 No tenemos la información de la convocatoria

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1 Participantes

RIJKSUNIVERSITEIT GRONINGEN

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Líder del proyecto

RIJKSUNIVERSITEIT GRONINGEN No se ha especificado una descripción o un objeto social para esta compañía.

TRL 4-5

Presupuesto del proyecto 2M€

Fecha límite de participación Sin fecha límite de participación.

Descripción del proyecto Sustainability in chemical synthesis requires that new methods and replacements for unsustainable existing methodologies should, where possible, focus on environmentally benign, atom- and energy-efficient processes that do not rely on toxic/precious metals. In this research program the focus is on the development of new sustainable and environmentally benign methodologies for selective oxidative transformations based on primarily first row transition metals using H2O2, O2 or electrochemical methods and on the tools required to obtain kinetic and mechanistic information that can further method development. The overall aim is to achieve selectivity and reactivity under mild, atom efficient conditions using non-toxic catalysts. In the research program mechanistic investigations run parallel with the development of synthetic methodologies, providing a perfect opportunity to combine very different skill sets towards a common goal. Five distinct approaches will be taken aimed at increasing the repertoire of selective methods available for catalytic organic oxidative functional group transformations with the key goal of sustainability in chemical synthesis through atom efficiency and selectivity. Furthermore, a systems approach will be taken in mechanistic studies where understanding the role(s) played by each reaction component involved, including metals, ligands, oxidant, solvent, additives, substrates and product(s), will be central. Importantly the development of new techniques and approaches to mechanistic studies and reaction monitoring, including Raman detection in flow reactors and UV Raman spectroscopy, are an integral part of the program. The research program is divided into four interrelated projects, which will run concurrently and be undertaken by one each of the PhD students involved and a smaller fifth project that is exploratory and high risk. As the project will fund the applicant for 50% of his time, this will enable him to take an active part.

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