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NMRSOFC

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In Operando Solid State Nuclear Magnetic Resonance Spectroscopy Studies of Anion...

In Operando Solid State Nuclear Magnetic Resonance Spectroscopy Studies of Anionic Conductors for Solid Oxide Fuel Cell Energy consumption and production that rely on fossil fuels is forecast to have a severe future impact on world economics and ecology. Electrochemical energy production is under serious consideration as an alternative energy/power... ver más

28/02/2013

THE CHANCELLOR MAS...

210K€

Presupuesto del proyecto: 210K€

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THE CHANCELLOR MASTERS AND SCHOLARS OF THE UN... No se ha especificado una descripción o un objeto social para esta compañía.

TRL 4-5

Fecha límite participación Sin fecha límite de participación.

Financiación concedida El organismo FP7 notifico la concesión del proyecto el día 2013-02-28 No tenemos la información de la convocatoria

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Líder del proyecto

THE CHANCELLOR MASTERS AND SCHOLARS OF THE UN... No se ha especificado una descripción o un objeto social para esta compañía.

TRL 4-5

Presupuesto del proyecto 210K€

Fecha límite de participación Sin fecha límite de participación.

Descripción del proyecto Energy consumption and production that rely on fossil fuels is forecast to have a severe future impact on world economics and ecology. Electrochemical energy production is under serious consideration as an alternative energy/power source. Systems for electrochemical energy storage and production include batteries and fuel cells, the latter being of greater interest due to the higher availability. Fuel cells are typically classified by the type of electrolyte. The Solid Oxide Fuel Cell (SOFC), where the electrolyte is a solid, has been proposed as the most effective choice due to its versatile choice of fuel, almost quantitative thermodynamic efficiency and tolerance to most impurities. Nevertheless, limitations and problems arise from the high operating temperatures (700 °C) and very humid atmospheres (pH2O = 0.5), which are largely due to the low anionic O2- and protonic H+ conductivities of anionic conductors electrolyte materials. Overall SOFC improvement relies on increasing the conductivities of the electrolyte, which could only be obtained from a mechanism understanding of how O2- and H+ propagate through the electrolyte. We proposed here to tackle these issues by studying the structural chemistry and O2- / H+ dynamics of electrolyte materials under in operando SOFC conditions using Nuclear Magnetic Resonance (NMR) spectroscopy, the most powerful structural determination technique available. The approach will rely on the combined use of state of the art very high field NMR spectrometers, robust solid state NMR probes capable of performing NMR experiments up to 800 °C and endless lists of NMR experiments to obtain structural data and dynamics models covering all timescales. In combination with other in operando techniques (XAS, AC), we aim to obtain mechanisms of conduction subsequently used to design better electrolytes materials with higher conductivities properties compatible with the manufacturing of fuel cells operating at lower temperatures.

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