Innovating Works

OXYPOW

Financiado
Harnessing the electrochemical power of oxygen
The recent discovery of anionic redox chemistry has unveiled a new transformational paradigm for designing sustainable rechargeable batteries with superior energy density. Li-rich layered oxide (LLO) cathodes exhibiting oxygen red... The recent discovery of anionic redox chemistry has unveiled a new transformational paradigm for designing sustainable rechargeable batteries with superior energy density. Li-rich layered oxide (LLO) cathodes exhibiting oxygen redox activity can deliver exceptional capacities (> 40% higher than state-of-the-art NMC811), due to the cumulative cationic and anionic redox processes. However, the LLOs suffer from poor energy efficiency, reduced power density and voltage decay, caused by progressive irreversible migration and trapping of transition metals in intermediate sites in the structure during operation. In this context, the aim of the project is to target new LLO polymorphs with improved stability and performance through crystal engineering of the oxygen stacking sequence and tuning of local cation-cation interactions. First, I will leverage my expertise in in situ X-ray/neutron diffraction and total scattering methods to study the evolution of the atomic structure (average and local) during synthesis of selected LLO compositions. This will (1) dramatically reduce the time needed to cover parameter space, (2) facilitate identification of the optimal reaction conditions for specific LLO polymorphs, and (3) provide fundamental mechanistic insight. Secondly, this information will be used to target LLOs with different structural configurations and systematically examine the relationship between their electrochemical performance and structural evolution during operation. Thirdly, I will investigate the charge compensation mechanisms (cationic and anionic) of the materials, which will be related to the structural changes as well as electrochemical data to yield a complete mechanistic picture of the synthesis-structure-property relationship in the system. This fundamental groundwork will allow development of a fabrication strategy for the next generation of sustainable high-performance cathode materials exploiting the untapped electrochemical potential of oxygen. ver más
31/08/2025
181K€
Duración del proyecto: 36 meses Fecha Inicio: 2022-08-03
Fecha Fin: 2025-08-31

Línea de financiación: concedida

El organismo HORIZON EUROPE notifico la concesión del proyecto el día 2022-08-03
Línea de financiación objetivo El proyecto se financió a través de la siguiente ayuda:
Presupuesto El presupuesto total del proyecto asciende a 181K€
Líder del proyecto
AGENCIA ESTATAL CONSEJO SUPERIOR DE INVESTIGA... Investigaciones agrarias
Perfil tecnológico TRL 2-3 552M