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Directed Evolution of Function within Chemical Systems Adaptive Capsules and Po...

Directed Evolution of Function within Chemical Systems Adaptive Capsules and Polymers A signature trait of living systems is their ability to dynamically adjust to features of their environments, adapting to stay alive, and evolving to take better advantage of the resources in their environments. This proposed rese... ver más

31/12/2016

THE CHANCELLOR MAS...

1M€

Presupuesto del proyecto: 1M€

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THE CHANCELLOR MASTERS AND SCHOLARS OF THE UN... No se ha especificado una descripción o un objeto social para esta compañía.

TRL 4-5

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Financiación concedida El organismo FP7 notifico la concesión del proyecto el día 2016-12-31 No tenemos la información de la convocatoria

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THE CHANCELLOR MASTERS AND SCHOLARS OF THE UN... No se ha especificado una descripción o un objeto social para esta compañía.

TRL 4-5

Presupuesto del proyecto 1M€

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Descripción del proyecto A signature trait of living systems is their ability to dynamically adjust to features of their environments, adapting to stay alive, and evolving to take better advantage of the resources in their environments. This proposed research aims to synthesise new chemical systems that are capable of adaptation and evolution, with the achievement of specified functions being used as the benchmarks by which we may be judged to have succeeded in setting the direction for our systems evolution. Two parallel lines of inquiry will be followed. First, we will build upon results that we have recently published in Science[1] to create a series of new molecular capsules that are capable of dynamically adapting to different guest molecules. These capsules will serve as sensors and as enzyme-like catalysts through the use of transition-state-analogue guests. Second, we will prepare new metal-containing conjugated polymers through self-assembly, which will be capable of dynamically exchanging building blocks in solution. These polymers will have potential applications as electrically-conductive materials, with functional properties that may be tuned and optimised by the application of evolutionary pressures. The success of these studies will thus create novel materials with uses as self-assembled sensors, catalysts, and electrical conductors. We will also shed light upon the question of how chemical systems may be induced to evolve under selective pressure. These studies thus have long-term bearing upon the questions of how living systems evolved from pre-biological mixtures of molecules. [1] P. Mal, B. Breiner, K. Rissanen, J.R. Nitschke, Science 2009, 324, 1697-1699.

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