NoNaCat
Financiado
Development of Molecular defined Non noble Metal Complexes and Nano structured M...
Development of Molecular defined Non noble Metal Complexes and Nano structured Materials for Sustainable Redox Reactions Development of Molecular defined Non noble Metal Complexes and Nano structured
The major objective of this proposal is the development of new active and selective catalysts based on earth abundant metals (e.g. Fe, Mn, Co, Cu). These catalysts will be used for improved synthetic transformations which are of i...
The major objective of this proposal is the development of new active and selective catalysts based on earth abundant metals (e.g. Fe, Mn, Co, Cu). These catalysts will be used for improved synthetic transformations which are of interest for organic chemistry in general and which are also of significant practical value for the chemical and life science industries. Traditional catalysts based on non-noble metals are not efficient for hydrogenation and dehydrogenation processes under mild conditions. However, by creating a suitable microenvironment with M-N interactions they are becoming active and selective. According to our concept the suitable surrounding will be created either by using nitrogen-containing pincer ligands or nitrogen-doped graphenes. Consequently, a variety of both molecular-defined homogeneous catalysts as well as nano-structured heterogeneous materials will be prepared, characterized and tested in various catalytic applications. More specifically, the following redox transformations will be investigated: Hydrogenation and transfer hydrogenation of carboxylic acids, esters, and nitriles; hydrogenation of amides and peptides; hydrogenation of carbon dioxide and selective oxidative coupling of alcohols to esters, amides, and nitriles. Furthermore, waste-free carbon-carbon bond forming reactions such as alkylations with alcohols and domino-synthesis of heterocycles from alcohols will be exploited. Finally, homogeneous and heterogeneous catalysts from earth abundant metals will be used in industrially relevant oxidative carbonylation reactions. With respect to methodology this proposal combines homogeneous with heterogeneous catalysis, which will result in new ideas for both fields.
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Duración del proyecto: 72 meses
Fecha Inicio: 2015-11-10
Fecha Fin: 2021-11-30
Fecha Fin: 2021-11-30
Línea de financiación: concedida
El organismo H2020 notifico la concesión del proyecto el día 2021-11-30
Línea de financiación objetivo
El proyecto se financió a través de la siguiente ayuda:
ERC-ADG-2014:
ERC Advanced Grant
Cerrada
hace 10 años
Presupuesto
El presupuesto total del proyecto asciende a
2M€
Líder del proyecto
LEIBNIZ INSTITUT FUER KATALYSE EV
No se ha especificado una descripción o un objeto social para esta compañía.
Perfil tecnológico
TRL
4-5
Perfil tecnológico
TRL
4-5
1.19M€ |
Participante