Design and Self Assembly of Organometallic Based Polypnictogen Materials and Dis...
Design and Self Assembly of Organometallic Based Polypnictogen Materials and Discrete Nano sized Supramolecules
In view of current developments in the fields of porous materials and discrete nano-sized molecules and aggregates the lack of organometallic-based compounds acting as nodes together with functionalized organic linkers in such mat...
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Descripción del proyecto
In view of current developments in the fields of porous materials and discrete nano-sized molecules and aggregates the lack of organometallic-based compounds acting as nodes together with functionalized organic linkers in such materials and as linkers and building blocks for nano-sized spheres and aggregates is obvious. By using organometallic polyphosphorus compounds it was possible to synthesize unprecedented prototypes of such materials and molecular nano-sized superspheres. These ground-breaking discoveries will be subsequently further developed to excess a qualitatively novel level of research by using polypnictogen starting materials. Key targets will be the generation of rigid 3D organometallic-based materials, discrete supramolecular nano-sized aggregates (charged moiety approach) and novel fullerene-like supramolecules as nano-spheres, nano-capsules and nano-wheels (neutral moiety approach). Especially the latter approach will generate unprecedented spheres and molecules which are extreme in size and function as there are multifunctional binding sites; multi-magnetic properties; tuning templates in size; generating, encapsulating and releasing highly reactive intermediates and reaction components. Finally, the work will move beyond our knowledge of known structurally characterized fullerenes by the development of non-carbon based alternatives within and beyond the fullerene topology.