Circular hydrometallurgy for energy-transition metals
CIRMET will lead to a new approach to hydrometallurgy, called circular hydrometallurgy, with a focus on the design of energy-efficient flowsheets or unit processes that consume a minimum amount of reagents and produce virtually no...
CIRMET will lead to a new approach to hydrometallurgy, called circular hydrometallurgy, with a focus on the design of energy-efficient flowsheets or unit processes that consume a minimum amount of reagents and produce virtually no waste. CIRMET has the ambitious goal to replace the traditional, linear hydrometallurgical flowsheets for extraction and refining of the energy-transition metals cobalt and nickel into a next-generation, circular flowsheet, which (1) consumes no chemicals other than (green) hydrogen, water and carbon dioxide (taking advantage of the unique chemical properties of carbon dioxide); (2) uses the acid for the leaching process as a catalyst that is continually regenerated rather than consumed; (3) reduces the net consumption of acids and bases to virtually zero through ingenious manipulations of chemical equilibria via solvent extraction; and (4) comprises a virtually zero discharge of solid and liquid waste streams. As such, CIRMET can drastically reduce the environmental footprint of hydrometallurgical processes. To enable such circular flowsheets, a new theoretical chemical thermodynamic framework for multiphase electrolyte equilibria involving two immiscible liquids and innovative unit operations for sustainable metal and sulphur recovery are developed. Hydrometallurgical processes are approached from a molecular level. Liquid-liquid equilibria are modelled by Gibbs-energy-minimisation (GEM) methods, rather than by solving law-of-mass action (LMA) equations. The proof of concept of circular flowsheets is demonstrated for metal recovery from real, complex (rather than synthetic), impurity-bearing input streams: nickel laterites, cobalt-nickel sulphide ores, mixed hydroxide precipitate (MHP), and mixed sulphide precipitate (MSP). Only by combining these three mutually supporting spheres of innovation – (1) the thermodynamic framework, (2) the unit process level and (3) the general flowsheet sphere – can CIRMET be successful.ver más
Seleccionando "Aceptar todas las cookies" acepta el uso de cookies para ayudarnos a brindarle una mejor experiencia de usuario y para analizar el uso del sitio web. Al hacer clic en "Ajustar tus preferencias" puede elegir qué cookies permitir. Solo las cookies esenciales son necesarias para el correcto funcionamiento de nuestro sitio web y no se pueden rechazar.
Cookie settings
Nuestro sitio web almacena cuatro tipos de cookies. En cualquier momento puede elegir qué cookies acepta y cuáles rechaza. Puede obtener más información sobre qué son las cookies y qué tipos de cookies almacenamos en nuestra Política de cookies.
Son necesarias por razones técnicas. Sin ellas, este sitio web podría no funcionar correctamente.
Son necesarias para una funcionalidad específica en el sitio web. Sin ellos, algunas características pueden estar deshabilitadas.
Nos permite analizar el uso del sitio web y mejorar la experiencia del visitante.
Nos permite personalizar su experiencia y enviarle contenido y ofertas relevantes, en este sitio web y en otros sitios web.