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PUSH-IT

Financiado

Charge Separation A General Motif for the Activation and Catalytic Functionali...

Charge Separation A General Motif for the Activation and Catalytic Functionalization of Strong Bonds PUSH-IT aims to establish charge-separation within formal multiple bonds as a concept for the activation of strong bonds in redox catalysis. The project is motivated by sustainable chemistry and displays a bottom-up approach for... ver más

31/05/2026

USAAR

1M€

Presupuesto del proyecto: 1M€

Líder del proyecto

UNIVERSITAT DES SAARLANDES No se ha especificado una descripción o un objeto social para esta compañía.

TRL 4-5

Ver 2 Participantes

Financiación concedida El organismo H2020 notifico la concesión del proyecto el día 2020-09-11

Línea de financiación objetivo El proyecto se financió a través de la siguiente ayuda:

ERC-2020-STG: ERC STARTING GRANTS

I+D

Cerrada hace 5 años

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2 Participantes

USAAR

1.50M€ | Lider

ARTSAIA, S.L.

606.22K€ | Participante

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27-11-2024: DGIPYME En las últimas 48 horas el Organismo DGIPYME ha otorgado 1 concesiones

27-11-2024: FUNDACION-EOI En las últimas 48 horas el Organismo FUNDACION EOI ha otorgado 2 concesiones

Duración del proyecto: 68 meses Fecha Inicio: 2020-09-11
Fecha Fin: 2026-05-31

Líder del proyecto

UNIVERSITAT DES SAARLANDES

TRL 4-5

Presupuesto del proyecto 1M€

Descripción del proyecto PUSH-IT aims to establish charge-separation within formal multiple bonds as a concept for the activation of strong bonds in redox catalysis. The project is motivated by sustainable chemistry and displays a bottom-up approach for new methods relevant for chemical synthesis as well as chemical energy conversion and storage. Inspired by heterogeneous catalysis, we will push electrons through formal multiple bonds and translate new principles from main-group chemistry to metals, which readily change oxidation states. We propose these charge-separated, vicinal zwitterions as the activated key intermediates for the functionalization of strong bonds (C–C, C–H, C–O, N–H and O–H). Importantly, we anticipate complementary and hence hitherto elusive chemo- and regiodiscrimination to the state of the art due to the unprecedented nucleophilicity of these compounds. The targeted applications include both fine- and bulk chemical synthesis. The interdisciplinary project focuses on coordination chemistry and combines inorganic and organic synthesis with catalysis and advanced spectroscopy. High-end computational design will guide all experiments. More specifically, hitherto unknown vicinal zwitterions of an earth-abundant alkaline earth metal (magnesium), late transition metals (palladium, platinum, gold), and a non-toxic heavy p-block element (bismuth) with carbon (terminal carbides), nitrogen (terminal imides) and oxygen (terminal oxides) atoms will be isolated using innovative and novel synthetic approaches. With these new and exciting molecular coordination compounds in hand, we will establish the stoichiometric activation and functionalization of strong bonds and will develop catalytic redox cycles. Overall, this research project will introduce a novel mechanism for bond activation in catalysis, which will allow us to understand elementary steps on heterogeneous surfaces as well as invent new chemical transformations in homogeneous reaction media.

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