ClaN-Bi
Financiado
A general bismuth-based platform for the catalytic construction of carbon–nitrog...
A general bismuth-based platform for the catalytic construction of carbon–nitrogen bonds and beyond.
The amino moiety is a fundamental functional group with essential functions across the chemical and life sciences, including agrochemical and pharmaceutical research and manufacture, polymer chemistry, and biochemistry. Therefore,...
The amino moiety is a fundamental functional group with essential functions across the chemical and life sciences, including agrochemical and pharmaceutical research and manufacture, polymer chemistry, and biochemistry. Therefore, there is a well-acknowledged need for new and more sustainable methods to construct C-N bonds. Most procedures for C-N bond formation rely on the use of toxic and expensive transition metal catalysts, which are notoriously impeded by undesired β-hydride elimination and/or poor site selectivity. Consequently, the search for new and more sustainable catalytic paradigms in synthesis has shifted towards the main group elements. Bismuth was recently demonstrated to moonlight both as a noble or first row transition metal, displaying reactivity in 1-electron and 2-electron processes at will. This dichotomy in reactivity of low-valent Bi complexes could potentially be crucial in addressing the long-standing issues encountered in C–N bond formation. Thus, ClaN-Bi aims to discover and develop new catalytic C–N cross-coupling reactions to generate both aliphatic and aromatic amines by exploiting the new Bi(I)/(II)/(III) redox platform.
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Duración del proyecto: 25 meses
Fecha Inicio: 2023-03-21
Fecha Fin: 2025-04-30
Fecha Fin: 2025-04-30
Línea de financiación: concedida
El organismo HORIZON EUROPE notifico la concesión del proyecto el día 2023-03-21
Línea de financiación objetivo
El proyecto se financió a través de la siguiente ayuda:
HORIZON-MSCA-2022-PF-01-01:
MSCA Postdoctoral Fellowships 2022
Cerrada
hace 2 años
Presupuesto
El presupuesto total del proyecto asciende a
174K€
Líder del proyecto
MAX PLANCK INSTITUT FUER KOHLENFORSCHUNG
No se ha especificado una descripción o un objeto social para esta compañía.
Perfil tecnológico
TRL
4-5
Perfil tecnológico
TRL
4-5